Document Type

Article

Publication Date

2025

Publication Title

Journal of Chemical Crystallography

Keywords

crown ether, hydrogen bonding, crystal structure, Hirshfeld analysis

Abstract

The compound 1,4,7-trithia-10,13-diazacyclopentadecane-9,14-dione, 1, crystallizes in the space group P21/c with a = 9.3608(3) Å, b = 16.0333(5) Å, c = 9.5608(3) Å, β = 113.3521(14)°, and Z = 4. The title molecule forms chains via face-to-face N–HO hydrogen bonds. The structure of 1 is also compared to the previously reported oxygen analog, 1,4,7-trioxa-10,13-diazacyclopentadecane-9,14-dione.

Funding Source

This article was published Open Access thanks to a transformative agreement between Milner Library and Springer Nature.

DOI

10.1007/s10870-025-01054-5

Comments

First published in Journal of Chemical Crystallography (2025): https://doi.org/10.1007/s10870-025-01054-5

Supplemental data attached.

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