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Graduation Term
2014
Degree Name
Master of Science (MS)
Department
Department of Chemistry
Committee Chair
Craig C. McLauchlan
Abstract
A series of vanadium(IV) dimers have been synthesized that bear bridging phosph(on/in)ate ligands with varying substituents, and terminal methoxy and ethoxy Kläui ligands [CpPOR,ORCo]–, R=Me, Et, resulting in two VO6 centers per complex. The complexes have been widely characterized, employing techniques such as spectroscopy, X-ray diffraction, and electrochemical analysis. The oxidative catalytic activity of each complex on the oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butyl-o-benzoquinone under aerobic conditions is presented herein.
Access Type
Thesis-ISU Access Only
Recommended Citation
Tarlton, Michael Lloyd, "Synthesis, Characterization and Oxidative Catalytic Activity of Vanadium ( Iv ) Complexes with Bridging Phosph ( on / in ) Ate, and Terminal Η 5-Cyclopentadienyltris ( Di ( Ethyl / Methyl ) Phosphito-κ1 P ) Cobaltate ( Iii ) Ligands" (2014). Theses and Dissertations. 266.
https://ir.library.illinoisstate.edu/etd/266
DOI
http://doi.org/10.30707/ETD2014.Tarlton.M