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Theses/Dissertations from 2024

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Optimization of a Sers-Based Vertical Flow Immunoassay Utilizing a Plasmonic Syringe Filter for Rapid Biomarker Detection and Quantification, Anthony Abeiku Amissah

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O-Alkylated Carbinolamides: Mechanistic Imperatives for a Motif Lacking Labile Protons, Thomas Christopher Arndt

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Rapid, Direct Screening of Priority Metal Contaminants in Environmental Systems with Reactive 3 D-Printed Cone Spray Ionization-Mass Spectrometry ( 3 D- Pcsi-Ms ), Jonathan Nzubechi Chilaka

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Utilizing B-n, B-o, and B-f Interactions toward Novel ( 5+2 ) Cycloadditions, Seth Ian Corrie

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Redefining the Scope of the Curtius Reaction via a Dehomologation of Carboxylic Acids Bearing an Alpha Leaving Group. Determining the Stereoelectronic Limitations of the Crimmins Anti-selective Asymmetric Glycolate Aldol Addition Reaction., Joy Odeh

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Site-Specific Conjugation of Antibodies with Peptides Mediated by Microbial Transglutaminase ( Mtg ) for Adsorption to Gold Nanoparticles, Kwame Osei

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Amide Assisted Dearomative Intramolecular Oxidopyrylium Based ( 5+2 ) Cycloaddition Reactions, IFEANYICHUKWU EMMANUEL PROMISE

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Insights Derived in Silico on the Nature of the Halogen · · · Halogen Bond at Ordered Surface Interfaces, Jarrod George Sage

Theses/Dissertations from 2023

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Temporal and Spatial Profiling of Priority Soil Pollutants Using Filter Cone Spray Ionization-Mass Spectrometry ( Fcsi-ms ), Rosemary Addo

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The Development of an Effective Synthetic Pathway to the Hiv Protease Inhibitor Darunavir and Its Structural Derivatives for Sar Studies via an Asymmetric Glycolate Aldol Addition Reaction Approach, Emmanuel Ayim

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Nitrogen Tethers as a Route to Net Intermolecular Silylox Ypyrone-Based Oxidopyrylium-Alkene [ 5 + 2 ] Cycloadditions, Andy M. Barnes

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Investigation of Intramolecular Oxidopyrylium-Based [ 5 +2 ] Cycloadditions, Kwabena Darko

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Dearomative | Amide | N-o Tethered Oxidopyrylium [ 5 + 2 ] Cycloaddition Reactions, Marymoud Erzuah

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Tunable Sns-imine Ligated Complexes of Copper and Nickel: Apllication in Photocatalytic Water Remediation, Temitayo Oluwayinka FALOLA

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Acyl Derivatives of Α-hydroxyhippuric Acid: Comparison of a Charged Substrate vs a Neutral Substrate for the Aqueous Kinetics, Elise Kerkemeyer

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Electron Affinity Equilibrium Studies of Synthesized N 1-and N 2-Phenyl-1,2,3-Triazole Isomers through Potassium Metal Reduction, Joe Santarelli

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Characterizing the Editing Modes of Duplicated Leucyl-Trna Synthetases in the Archaea Sulfolobus Islandicus, Evan T. Strandquist

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An ( R )-4-Phenyl-1,3-oxazolidine-2-Thione Mediated Approach to 2, 3-Disubstituted Oxetanes and the Key Hydroxyethyl Isostere of the Hiv Protease Inhibitor Darunavir. Preparation of Non-evans Syn Glycolate Aldol Addition Products. a New Direction for the Curtius Rearrangement in the Dehomologation of Alpha-alkoxycarboxylic Acids, Jordan Michael Witte

Theses/Dissertations from 2022

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Establishing the Non-canonical Nature of a Leucyl-Trna Synthetase Paralog in Sulfolobus Islandicus, Jonathan Blair Brewster

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Sers-Based Rapid Vertical Flow Immunoassay for Enhanced Point of Care Diagnostics, Eunice Ama Ebbah

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Synthesis of Highly Conjugated Porphyrinoid Systems, Melissa Mathius

Theses/Dissertations from 2021

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Synthesis of Oxyquinoliziniporphyrins and Pyridoquinoliziniporphyrins, Emma Cramer

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Effects of Crosslinking Density in the Formation of Gold-Polymer Composite Particles and Their Catalytic Applications, Franklin Obinna Egemole

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Investigation and Application of Oxidopyrylium-Based [ 5 +2 ] Cycloadditions and the Development of Novel Synthetic Strategies, Jake Grabowski

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Improving Sers Detection of Illicit Drugs Using a Plasmonic Substrate Modified with Self-Assembled Monolayers, John Harms

Theses/Dissertations from 2020

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Efforts towards the Formal Synthesis of the Akaji Human T-cell Leukemia Virus Type 1 ( Htlv-1 ) Protease Inhibitor via an Asymmetric Glycolate Aldol Addition Route, Marian Aba Addo

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Investigating the Reversibility of Protein Adsorption on Gold Nanoparticles and the Role of Free Thiol, Awosiji Olatunde Awotunde

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First Report of a Potential Mycosporine-like Amino Acid Extracted from Agave: Implications for New Sunscreen Additives, McKenzie Nicole Biswell

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Rapid Vertical Flow Assay on Aunp Plasmonic Paper for Sers-Based Point of Need Diagnostics, Richard Frimpong

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Optically Active Gold-Based Composite Particles for Sensing and Catalytic Applications, Jemima Asi Lartey

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Oxadiazinones as Chiral Auxiliaries: Chiral Templates for Asymmetric Conjugate Addition in the Synthesis of ( R )-( + )-Tolterodine, Fatima Olayemi Obe

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Adsorption Behavior of Chemically / Charged Modified Antibodies on Gold Nanoparticles, Samuel Okyem

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Aqueous Kinetics of Α-hydroxyhippuric Acid Derivatives Bearing Electron-Withdrawing Groups as a Function of Ph and Buffer Catalysts, Mohamad Imad Rafie

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The Development of a New Entry Point into Enantiomerically Enriched Sulfinyl Derivatives, Jessica Shaw

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Development and Characterization of Robust Methods for Field Investigations with Portable Mass Spectrometry, Ashley Rose Stelmack

Theses/Dissertations from 2019

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Potential for on-Site, Prosecutorial Evidence from Drug Residues Collected on Plasmonic Paper: a Pilot Study for Sers-Psi-ms, Daniel S. Burr

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In Situ Encapsulation of Gold Nanoparticles into Stimuli-responsive Polymer Particles for Catalytic Applications, Pascal Nnaemeka Eyimegwu

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Modified Ambient Mass Spectrometric Methods for Field Screening and Confirmation of Forensic Evidence, William Lee Fatigante

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Synthesis and Metalation of Internally Alkylated Porphyrinoids, Alissa Nicole Latham

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Syntheses, Characterization, and Preliminary Evaluation of Potential Ruthenium Anticancer Complexes Containing Schiff Base Ligands, Stephen Mensah

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Effects of Electrical Stimulation on Glioma Cells in Vitro with Implications for Treating Chronic Pain: Development of a Model System, David C. Platt

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Development of 31 P Nmr Assay for the Kinetic Evaluation of Recombinant Choline Kinase from Leishmania Infantum, Jacob A. Walker

Theses/Dissertations from 2018

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Alkyne Combustion: Experimental and Computational Studies of Formyl Radical Production, Matthew Charles Drummer

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Optimization of Ambient Ionization Methodologies for Field Investigations Utilizing Portable Mass Spectrometric Instrumentation, Shahnaz Mukta

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Synthesis and Characterization of a Series of Vanadium ( Iv ) Complexes with the Kläui Ligand, Xiao Wu

Theses/Dissertations from 2017

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The Biochemical Assessment of Two Secreted Acid Phosphatases from Leishmania Tarentolae, Their Response to Electric Fields, Glycosidase Incubation, and / or Vanadium, Benjamin M. Dorsey

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Formation, Characterization, and Optimization of Antibody-Gold Nanoparticle Conjugates, Seth L. Filbrun

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Fermenting Solutions to New World Problems: Bioremediation of Blue Agave and Cocoa Pod Wastes, Daniel Hart

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Efforts towards the Synthesis of an Htlv-1 Protease Inhibitor: Synthesis, Spectroscopic Analysis, and Computational Study of Asymmetric Aldol Products Derived from N3-( P-Methoxyphenoxy ) Acetyloxazolidine- 2-Thione, Craig Steven Haynes

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Synthesis and Characterization of Mixed Donor Ligands and Their Corresponding Metal Complexes, Timothy Michael Erasmus Jugovic

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Kinetic Characterization of Listeria Monocytogenes 2-C- Methyl-D-erythritol 4-Phosphate Cytidylyltransferase ( Cms ) Enzymes Using High Performance Liquid Chromatography ( Hplc ), Mark Oblazny

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Development of New Routes for the Synthesis of Carbaporphyrins and Carbachlorins, Navneet Sahota

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Synthesis, Characterization, and Growth Inhibition of Vanadium Complexes with Leishmania Tarentolae, Craig Alexander Wallace

Theses/Dissertations from 2016

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Synthesis and Characterization of Polycyclic Aromatic Hydrocarbon ( Pah )-Porphyrin Hybrids, Ruixiao Gao

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Inhibitory Effects of Unique Sulfonamides on Leishmania Tarentolae and Potential Pathway of Inhibition, Jade M. Katinas

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Solid State Synthesis and Characterization of the Rare Earth-Free Anti-perovskites Sr2.5-Xba0.5 Al1-Xp Xo4 F ( 0 ≤ X ≤ 0.15 ), Sr3al1-Xy Xo 4 F ( 0 ≤ X ≤ 1 ), and Sr2.5-x/2ba0.5 Al1-Xhfxo4 F ( 0 ≤ X ≤ 0.1 ) as Potential Phosphor Materials, Sean Thomas Keil

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Analytical Validation of a Portable Mass Spectrometer System for High Throughput Forensic Screening, Zachary Earl Lawton

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A Comparative Study of Isocyanates and Isothiocyanates via One Electron Reduction, Mark Alan Servos

Theses/Dissertations from 2015

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Synthesis and Characterization of Neo-Confused Porphyrins and Related Systems, Arwa Salem Almejbel

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Transition Metal-Olefin Bonding Interactions: a Density Functional Theory Study [ M ( Co ) X ( Æ? 2-C 2 H 3-C 6 H 4-Y) ], Michael John Berninger

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Characterization of Cytidylyltransferase Enzyme Activity through High Performance Liquid Chromatography, James Brault

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Synthesis and Characterization of Naphthocarbaporphyrins and Related Systems, Eric Grabowski

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Synthesis, Characterization and Reactivty of Novel Supraoctahedral Hexarhenium Clusters and Use of Silver N-heterocyclic Carbene Transfer Reagents, Daniel N. Huh

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An Approach to an Agave Problem: the Bioremediation of Agricultural Waste by Yeast Fermentations, Joshua Michael Jarodsky

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Utilization of Antibody-Conjugated Gold Nanoparticles, Dynamic Light Scattering and Sers in Influenza Virus Detection, Yen Hoang Lai

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Investigation of Oxidopyrylium-Alkene [ 5 +2 ] Cycloaddition Conjugate Addition Cascades and Extension to Chiral Auxiliary-Based Variants, Chunyin Marshall Law

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Validation and Application of Ambient-Sampling, Portable Ms Systems for Forensic Analysis, Adam Edward O'Leary

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Synthesis and Characterization of Rare-Earth Free Doped Sr3 Mo4 F ( m= Al, Ga ) Anti-perovskite Compounds with Application to Led Lighting, Calvin Dakota Quilty

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Functional Expression and Characterization of a Truncated Candida Antarctica Lipase B in Yeast, Samantha Robinson

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Kinetic and Mechanistic Effects of Substituents on the Aldehyde Portion of N- ( Hydroxybenzyl ) Benzamides, Kurt Scott Tyminski

Computational Investigations Of Oxygen-Containing Donor-Acceptor Complexes Involving Sulfur Dioxide Or Sulfur Trioxide, George A. Van Den Driessche

Theses/Dissertations from 2014

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Synthesis of Novel Adj-Dicarbaporphyrinoid Systems and Theoretical Investigations into Porphyrinoid Aromaticity and Stability, Deyaa AbuSalim

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Bisphosphonate and Vanadium-Bisphosphonate Compounds as New Directions in the Treatment of Leishmaniasis, Amy Christensen

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Synthesis of Benziporphyrin Analogs and Carbaporphyrinoid Systems, Stacy Fosu

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Acyl Succiimides and Acyl Phthalimides as Tools for Organic Synthesis. Asymmetric Synthesis of an Htlv-1 Protease Inhibitor., Cassie Ann Goodman

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Examination of Quasienantiomers of Oxadiazinanones Which Fail To Fractionally Crystallize, Patricia Ann Higgins

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Development and Application of Sers Based Immunoassay Using a Gold Plated Membrane for Use in Flow-through Immunoassay, Michelle Ashely Penn

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Studies of Rhenium Based Clusters Containing Nitriles and Heterocyclic Ligands, YiXin Ren

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Fundamental Investigations of Pyranone Activation to Oxidopyrylium Intermediates and Corresponding [ 5 +2 ] Cycloaddition Processes, Justin Adam Simanis

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Synthesis, Characterization and Oxidative Catalytic Activity of Vanadium ( Iv ) Complexes with Bridging Phosph ( on / in ) Ate, and Terminal Η 5-Cyclopentadienyltris ( Di ( Ethyl / Methyl ) Phosphito-κ1 P ) Cobaltate ( Iii ) Ligands, Michael Lloyd Tarlton

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Synthesis, Characterization, and Reactivity of Hexarhenium Selenide Cluster Complexes Containing Carbon-Coordinating Ligands, Wade Bruce Wilson

Theses/Dissertations from 2013

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Α-Hydroxyhippuric Acid Derivatives: Ph-dependent Aqueous Kinetics and Buffer Catalysis., Kati Feken

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Application of Ambient Mass Spectrometry for the Detection of Emerging Organic and Inorganic Environmental Contaminants, Jamie Nizzia